JOURNAL ARTICLE

Direct Preparation of Activated Carbon from Coal and its Electrochemical Properties for Electric Double Layer Capacitor

Ming Dong ZhengXiaoyong ZhangRu Chun LiMing Bo WuYe Jing GengXiao Jun He

Year: 2011 Journal:   Advanced materials research Vol: 197-198 Pages: 1253-1257   Publisher: Trans Tech Publications

Abstract

Direct preparation of activated carbon (AC) from coal was reported by microwave heating with potassium hydroxide as activation agent. Electrochemical properties of AC electrodes were investigated by cyclic voltammetry, constant current charge–discharge. The results show that functional groups on AC include –C=O, –O–H and –C–O. The micropore volume of AC from different coal totals 48.5–95.6%. The total pore volume of AC from different coal passes through a maximum with the decrease of volatile mater content in coal. The specific surface area and total pore volume of AC from Qing ting coal reach 1874 m 2 g -1 and 1.00 cm 3 g -1 , respectively. The specific capacitance and energy density of AC from higher coal rank is usually bigger than that of AC from lower coal rank.

Keywords:
Potassium hydroxide Coal Activated carbon Materials science Electrochemistry Microporous material Capacitance Volume (thermodynamics) Cyclic voltammetry Electrode Carbon fibers Current density Specific surface area Carbonization Porosity Chemical engineering Adsorption Analytical Chemistry (journal) Chemistry Composite material Scanning electron microscope Organic chemistry Catalysis Physical chemistry

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