Selective Stobbe condensation under solvent-free conditions

Koichi Tanaka; Teizo Sugino; Fumio Toda

doi:10.1039/b006565j

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Selective Stobbe condensation under solvent-free conditions

Koichi Tanaka Teizo Sugino Fumio Toda

Year: 2000 Journal: Green Chemistry Vol: 2 (6)Pages: 303-304 Publisher: Royal Society of Chemistry

DOI: 10.1039/b006565j

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Abstract

Solvent-free condensation of cyclohexanone (1) and diethyl succinate (2) in the presence of ButOK at room temperature gives cyclohexylidenesuccinic acid (3), while heating a mixture of 1, 2 and ButOK at 80 °C gives only cyclohexenylsuccinic acid (4).

Keywords:

Cyclohexanone Condensation Chemistry Solvent Organic chemistry Polymer chemistry Thermodynamics Catalysis

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Synthetic Organic Chemistry Methods

Physical Sciences → Chemistry → Organic Chemistry

Chemical Synthesis and Analysis

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Synthesis and properties of polymers

Physical Sciences → Materials Science → Polymers and Plastics

Selective Stobbe condensation under solvent-free conditions

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