M3Ni3Sb4 (M = Zr, Hf) and Zr3Pt3Sb4. Ternary Antimonides with the Y3Au3Sb4 Structure

Meitian Wang; Robert McDonald; Arthur Mar

doi:10.1021/ic990144i

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M₃Ni₃Sb₄ (M = Zr, Hf) and Zr₃Pt₃Sb₄. Ternary Antimonides with the Y₃Au₃Sb₄ Structure

Meitian Wang Robert McDonald Arthur Mar

Year: 1999 Journal: Inorganic Chemistry Vol: 38 (14)Pages: 3435-3438 Publisher: American Chemical Society

DOI: 10.1021/ic990144i

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Abstract

The isostructural ternary antimonides Zr3Ni3Sb4, Hf3Ni3Sb4, and Zr3Pt3Sb4 have been synthesized by arc-melting. Zr3Ni3Sb4 adopts the Y3Au3Sb4-type structure, a filled variant of the Th3P4-type structure. A four-connected Zr−Ni metal−metal bonding network pervades the structure. Zr3Ni3Sb4 and its analogues represent the the first examples in the important class of compounds M3M'3Sb4 in which M is not an f-element or Y.

Keywords:

Isostructural Ternary operation Chemistry Crystallography Arc melting Metal Structure type Zirconium Crystal structure X-ray crystallography Antimonide Inorganic chemistry Physics Diffraction Microstructure

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Rare-earth and actinide compounds

Physical Sciences → Physics and Astronomy → Condensed Matter Physics

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Physical Sciences → Chemistry → Inorganic Chemistry

M₃Ni₃Sb₄ (M = Zr, Hf) and Zr₃Pt₃Sb₄. Ternary Antimonides with the Y₃Au₃Sb₄ Structure

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