Electrogenerated chemiluminescence of luminol in neutral and alkaline aqueous solutions on a silver nanoparticle self‐assembled gold electrode

Abstract

Abstract The electrochemiluminescence (ECL) behaviour of luminol on a silver nanoparticle self‐assembled gold electrode in neutral and alkaline solutions was investigated using conventional cyclic voltammetry (CV). The silver nanoparticle self‐assembled gold electrode exhibited excellent ECL properties for the luminol ECL system. In neutral solutions, four ECL peaks (ECL‐1–ECL‐4) were observed at 0.73, 1.15, ‐0.46 and ‐1.35 V (vs. SCE), respectively. The intensities of these peaks were enhanced significantly compared with those on a bulk gold electrode and a gold nanoparticle self‐assembled gold electrode. It was found that ECL‐1 and ECL‐2 on a silver nanoparticle‐modified electrode were about 1000 and 1770 times stronger than those on a bare Au electrode and were about 17 and 15 times stronger than those on a gold nanoparticle‐modified electrode, respectively. In alkaline solutions, four ECL peaks were also observed that were much stronger than those in neutral solutions, and ECL‐1 and ECL‐2 were enhanced by about three orders and one order of magnitude compared with those on a bare Au electrode and on a gold nanoparticle self‐assembled electrode, respectively. Moreover, the silver nanoparticle‐modified electrode exhibited good stability and reproducibility for luminol ECL. These peaks were found to depend on a number of factors, including silver nanoparticles on the surface of the modified electrode, potential scan direction, scan rate, scan range, the presence of O 2 or N 2 , pH values, the concentrations of NaBr and luminol, and buffer solutions. The emitter of the ECL was confirmed as 3‐aminophthalate by analysing the CL spectra. The surface state of the silver nanoparticle self‐assembled electrode was characterized by scanning electron microscopy (SEM) and the interface property of the electrode was studied by electrochemical impedance spectroscopy (EIS). A mechanism for the formation of these ECL peaks is proposed. The results demonstrate that luminol has excellent ECL properties, such as strong ECL intensity and good reproducibility on a silver nanoparticle‐modified gold electrode, in both neutral and alkaline solutions, which is of great potential in analytical applications. Copyright © 2006 John Wiley & Sons, Ltd.