JOURNAL ARTICLE

Synthese und Kristallstruktur von [N(Hex)4][Cu2(CN)3]

Thorsten PretschI. BrüdgamH. Hartl

Year: 2003 Journal:   Zeitschrift für anorganische und allgemeine Chemie Vol: 629 (6)Pages: 942-944   Publisher: Wiley

Abstract

Abstract Synthesis and Crystal Structure of [N(Hex) 4 ] [Cu 2 (CN) 3 ] [N(Hex) 4 ] [Cu 2 (CN) 3 ] has been prepared by solvothermal reaction of CuCN with Tetra‐ n ‐hexylammoniumiodide in acetone. The crystal structure is built up by condensed (CuCN) 6 and (CuCN) 7 rings, forming a zeolith type cyanocuprate(I) framework [Cu 2 (CN) 3 — ]. Space group R 3; α = 44.482(6), c = 21.283(4) Å, V = 36471(9) Å 3 ; Z = 9.

Keywords:
Crystal structure Chemistry Acetone Crystallography Organic chemistry

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Citation History

Topics

Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Lanthanide and Transition Metal Complexes
Physical Sciences →  Materials Science →  Materials Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry

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