Synthese und Struktur eines aminstabilisierten Sulfens, RHC=SO2 · N(CH2CH2)3CH / Synthesis and Structure of an Amine Stabilized Sulfene, RHC=SO2 · N(CH2CH2)3CH

Uwe Hartwig; Hans Pritzkow; Wolfgang Sundermeyer; Joachim Waldi

doi:10.1515/znb-1988-0306

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Synthese und Struktur eines aminstabilisierten Sulfens, RHC=SO₂ · N(CH₂CH₂)₃CH / Synthesis and Structure of an Amine Stabilized Sulfene, RHC=SO₂ · N(CH₂CH₂)₃CH

Uwe Hartwig Hans Pritzkow Wolfgang Sundermeyer Joachim Waldi

Year: 1988 Journal: Zeitschrift für Naturforschung B Vol: 43 (3)Pages: 271-274 Publisher: De Gruyter

DOI: 10.1515/znb-1988-0306

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Abstract

The structure of the quinuclidine-stabilized mesyl sulfene H 3 C-SO 2 -CH=SO 2 ←N(CH 2 CH 2 ) 3 CH (3) was determined by X-ray analysis, which indicates a double-bond in the C=SO 2 group, while the quinuclidine is coordinated at a distance to the sulfur atom longer than a S-N single bond.

Keywords:

Quinuclidine Chemistry Amine gas treating Crystal structure Stereochemistry Crystallography Medicinal chemistry Organic chemistry

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Sulfur-Based Synthesis Techniques

Physical Sciences → Chemistry → Organic Chemistry

Chemical Reactions and Mechanisms

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Synthese und Struktur eines aminstabilisierten Sulfens, RHC=SO₂ · N(CH₂CH₂)₃CH / Synthesis and Structure of an Amine Stabilized Sulfene, RHC=SO₂ · N(CH₂CH₂)₃CH

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