Facile synthesis of cone p-tert-butylcalix[4]arene-crown conformers

Е. А. Алексеева; S.S. Basok; Alexander V. Mazepa; Andrei I. Gren

doi:10.1016/j.mencom.2007.11.010

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Facile synthesis of cone p-tert-butylcalix[4]arene-crown conformers

Е. А. Алексеева S.S. Basok Alexander V. Mazepa Andrei I. Gren

Year: 2007 Journal: Mendeleev Communications Vol: 17 (6)Pages: 330-331 Publisher: Elsevier BV

DOI: 10.1016/j.mencom.2007.11.010

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Abstract

The series of p-tert-butylcalix[4]arene-crowns in the cone conformation was synthesised in high yields under conditions producing disubstituted calix[4]arenes in the presence of K2CO3 in acetonitrile; the formation of calix-bis(crown)s and doubly(calix)-doubly(crown) in these reactions was established.

Keywords:

Chemistry Crown (dentistry) Conformational isomerism Calixarene Acetonitrile Cone (formal languages) Medicinal chemistry Stereochemistry Crystallography Organic chemistry Molecule

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Supramolecular Chemistry and Complexes

Physical Sciences → Chemistry → Organic Chemistry

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Physical Sciences → Materials Science → Materials Chemistry

Facile synthesis of cone p-tert-butylcalix[4]arene-crown conformers

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