Neue Synthesen und Kristallstrukturen von Bis(fluorphenyl)quecksilber, Hg(Rf)2 (Rf = C6F5, 2, 3, 4, 6‐F4C6H, 2, 3, 5, 6‐F4C6H, 2, 4, 6‐F3C6H2, 2, 6‐F2C6H3)

Dieter Naumann; Frank Schulz

doi:10.1002/zaac.200400244

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Neue Synthesen und Kristallstrukturen von Bis(fluorphenyl)quecksilber, Hg(R_f)₂ (R_f = C₆F₅, 2, 3, 4, 6‐F₄C₆H, 2, 3, 5, 6‐F₄C₆H, 2, 4, 6‐F₃C₆H₂, 2, 6‐F₂C₆H₃)

Dieter Naumann Frank Schulz

Year: 2004 Journal: Zeitschrift für anorganische und allgemeine Chemie Vol: 631 (1)Pages: 122-125 Publisher: Wiley

DOI: 10.1002/zaac.200400244

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Abstract

Abstract Bis(fluorphenyl)quecksilber‐Verbindungen, Hg(R f ) 2 (R f = C 6 F 5 , C 6 HF 4 , C 6 H 2 F 3 , C 6 H 3 F 2 ), werden durch Reaktionen von HgF 2 mit Me 3 SiR f in sehr guten Ausbeuten dargestellt. Die Kristallstrukturen von Hg(2, 3, 4, 6‐F 4 C 6 H) 2 (monoklin, P 2 1 / n ), Hg(2, 3, 5, 6‐F 4 C 6 H) 2 (monoklin, C 2/ m ), Hg(2, 4, 6‐F 3 C 6 H 2 ) 2 (monoklin, P 2 1 / c ) und Hg(2, 6‐F 2 C 6 H 3 ) 2 (triklin, P 1) werden beschrieben.

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Crystal structure Chemistry Crystallography

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Inorganic Fluorides and Related Compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Fluorine in Organic Chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Pharmaceutical Science

Neue Synthesen und Kristallstrukturen von Bis(fluorphenyl)quecksilber, Hg(R_f)₂ (R_f = C₆F₅, 2, 3, 4, 6‐F₄C₆H, 2, 3, 5, 6‐F₄C₆H, 2, 4, 6‐F₃C₆H₂, 2, 6‐F₂C₆H₃)

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