JOURNAL ARTICLE

Evaluation of Equilibrium Sorption Isotherm Equations

Chiachung Chen

Year: 2013 Journal:   The Open Chemical Engineering Journal Vol: 7 (1)Pages: 24-44   Publisher: Bentham Science Publishers

Abstract

The sorption isotherm is important information for evaluating the ability of an adsorption system to treat the industrial waste water. In this study, eleven datasets from literatures were selected and three two-parameter and three-parameter equations were used to evaluate adsorption systems. Quantitative criteria included six error functions, and the quantitative criterion was residual plots. Isotherm constants differed by linearization and nonlinear regression analysis, especially for the three-parameter equations. The results indicated the inconsistent results of the error functions for select-ing the adequate equations. Residual plots were useful to observe the fitting ability of isotherm equations. Temperature has a significant effect on isotherm constants.

Keywords:
Linearization Residual Sorption Thermodynamics Mathematics Sorption isotherm Nonlinear system Nonlinear regression Adsorption Applied mathematics Chemistry Regression analysis Statistics Physics Physical chemistry Algorithm

Metrics

51
Cited By
1.72
FWCI (Field Weighted Citation Impact)
28
Refs
0.86
Citation Normalized Percentile
Is in top 1%
Is in top 10%

Citation History

Topics

Adsorption and biosorption for pollutant removal
Physical Sciences →  Environmental Science →  Water Science and Technology

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