Surface plasmon resonance spectroscopic comparison of spiroxazine monolayer and polymeric thin film

Abstract

Abstract Photochromic dye has recently attracted much interest in optical applications because of its reversible photoswitching properties by light irradiation. To apply those aspects of photochromism to actual photonic devices, the form of the thin film must be favorable to the photochromic molecular system. In this study, a polymeric thin film and self‐assembled monolayer were constructed with a photochromic spiroxazine derivative that is well known for its good fatigue properties. Their photoisomerization properties were characterized through surface plasmon resonance (SPR). As a result of ultraviolet irradiation to these thin films, the SPR angle shift clearly appeared as the optical thickness (Refractive index × Geometrical thickness) change in both of the films. The Fresnel calculation based on measurement results showed that the angle shift of the polymeric thin film mainly corresponded to the change of the refractive index. For the spiroxazine monolayer, the geometrical thickness change caused the resonance angle to shift dominantly. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3459–3465, 2003