Bright White Upconversion Emission from Tm³⁺/Yb³⁺/Er³⁺-Doped Lu₃Ga₅O₁₂ Nanocrystals

Abstract

We report the synthesis of Tm3+/Yb3+/Er3+-doped Lu3Ga5O12 nanocrystals prepared by a simple sol−gel method exhibiting bright white light following excitation with lower energy near-infrared light (λexc = 980 nm) via an upconversion process. The combination of upconverted blue (from Tm3+), green, and red (from Er3+) emissions resulted in the white luminescence, which is intense and visible to the naked eye at a laser power less than 30 mW (3.4 W/cm2). The calculated Commission internationale de l′éclairage (CIE) color coordinates, which is the standard reference for defining colors, fall well within the white region and shift only slightly with the incident laser powers indicating that the material might be promising for the development of devices such as white light lasers and LEDs.