JOURNAL ARTICLE

Palladium-Catalyzed Suzuki−Miyaura Cross-Couplings of Aryl Tosylates with Potassium Aryltrifluoroborates

Liang ZhangTianhao MengJie Wu

Year: 2007 Journal:   The Journal of Organic Chemistry Vol: 72 (24)Pages: 9346-9349   Publisher: American Chemical Society

Abstract

Pd-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl tosylates with potassium aryl trifluoroborate in the presence of bulky and electron-rich phosphine ligand is described. In addition, a useful chemoselective coupling of an aryl chloride in the presence of a tosyloxy group was demonstrated.

Keywords:
Chemistry Aryl Phosphine Palladium Catalysis Potassium Ligand (biochemistry) Coupling reaction Suzuki reaction Organic chemistry Chloride Medicinal chemistry Combinatorial chemistry Alkyl

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Citation History

Topics

Catalytic Cross-Coupling Reactions
Physical Sciences →  Chemistry →  Organic Chemistry
Chemical synthesis and alkaloids
Physical Sciences →  Chemistry →  Organic Chemistry
Organoboron and organosilicon chemistry
Physical Sciences →  Chemistry →  Organic Chemistry
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