ChemInform Abstract: Rhodium‐Catalyzed Asymmetric Coupling Reaction of Allylic Ethers with Arylboronic Acids.

Hiroyoshi Kiuchi; Dai Takahashi; Kenji Funaki; T. Sato; Shuichi Ôi

doi:10.1002/chin.201252022

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ChemInform Abstract: Rhodium‐Catalyzed Asymmetric Coupling Reaction of Allylic Ethers with Arylboronic Acids.

Hiroyoshi Kiuchi Dai Takahashi Kenji Funaki T. Sato Shuichi Ôi

Year: 2012 Journal: ChemInform Vol: 43 (52) Publisher: Wiley

DOI: 10.1002/chin.201252022

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Abstract

Abstract In the presence of an optimized catalytic system and an optimized ether leaving group, optically active branched alkenes are obtained with excellent regioselectivities and enantioselectivities.

Keywords:

Chemistry Allylic rearrangement Catalysis Rhodium Optically active Ether Coupling reaction Coupling (piping) Medicinal chemistry Combinatorial chemistry Organic chemistry

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Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Catalytic C–H Functionalization Methods

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

ChemInform Abstract: Rhodium‐Catalyzed Asymmetric Coupling Reaction of Allylic Ethers with Arylboronic Acids.

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