Toughened Poly(Trimethylene Terephthalate) by Blending with a Functionalized Metallocenic Poly(Ethylene-Octene) Copolymer

Abstract

New toughened poly(trimethylene terephthalate) (PTT) materials were obtained by melt blending with maleic anhydride grafted poly(ethylene-octene) (POEg). Rheological properties, mechanical properties, and morphological characteristics of PTT/POEg blends at four different compositions—95/5, 90/10, 80/20, and 70/30—were studied. The melt viscosity of the blends shows a linear decrease on increasing the POEg content. The addition of rubbery POEg to the PTT matrix increases the impact strength, while tensile properties decrease. Scanning electron microscopy (SEM) displayed a very good dispersion of POEg particles in the PTT matrix. Differential scanning colorimetry (DSC) experiments showed that for all samples the melting point was almost constant and the crystallinity did not show obvious differences. SEM results showed shear yielding of the PTT matrix was the major toughening mechanism.