Efficient Olefin Diboration by a Base-Free Platinum Catalyst

Carl N. Iverson; Milton R. Smith

doi:10.1021/om970199x

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Efficient Olefin Diboration by a Base-Free Platinum Catalyst

Carl N. Iverson Milton R. Smith

Year: 1997 Journal: Organometallics Vol: 16 (13)Pages: 2757-2759 Publisher: American Chemical Society

DOI: 10.1021/om970199x

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Abstract

Pt(NBE)3 and Pt(COD)2 (NBE = norbornene, COD = 1,5−cyclooctadiene) catalyze the addition of 2,2'-bis(1,3,2-benzodioxaborole) (CatB−BCat) to α-olefins. The reactions proceed smoothly under ambient conditions to give 1,2-diborylalkanes in high yield, and the catalyst is compatible with common functional groups.

Keywords:

Chemistry Catalysis Norbornene Platinum Olefin fiber Yield (engineering) Medicinal chemistry 1,5-Cyclooctadiene Base (topology) Organic chemistry Polymer chemistry Polymerization Polymer Metallurgy

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Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Boron Compounds in Chemistry

Health Sciences → Medicine → Radiology, Nuclear Medicine and Imaging

Chemical Synthesis and Analysis

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Efficient Olefin Diboration by a Base-Free Platinum Catalyst

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