The reactions of µ-amido-µ-hydroxodicobalt complexes with perchloric acid. Evidence for the formation of µ-perchlorato-complexes

Ross Taylor; A. Geoffrey Sykes

doi:10.1039/c29690001137

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The reactions of µ-amido-µ-hydroxodicobalt complexes with perchloric acid. Evidence for the formation of µ-perchlorato-complexes

Ross Taylor A. Geoffrey Sykes

Year: 1969 Journal: Journal of the Chemical Society D Chemical Communications Vol: 0 (19)Pages: 1137-1138

DOI: 10.1039/c29690001137

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Abstract

Changes in visible spectra which are observed when perchloric acid is added to solutions of the complexes (en)2Co·µ(NH2,OH)·Co(en)24+ and (NH3)4Co·µ(NH2,OH)·Co(NH3)44+ have led to the identification of perchlorato-complexes.

Keywords:

Perchloric acid Chemistry Medicinal chemistry Inorganic chemistry

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Molecular Sensors and Ion Detection

Physical Sciences → Chemistry → Spectroscopy

Chemical Analysis and Environmental Impact

Physical Sciences → Environmental Science → Health, Toxicology and Mutagenesis

Supramolecular Chemistry and Complexes

Physical Sciences → Chemistry → Organic Chemistry

The reactions of µ-amido-µ-hydroxodicobalt complexes with perchloric acid. Evidence for the formation of µ-perchlorato-complexes

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