Structure investigations of Tl(I)-arsenates(V): Tl3(AsO4), Tl2Cu(I)(AsO4) and TlCu(II)2(AsO4)(AsO3OH)

doi:10.1524/zkri.1998.213.1.42

JOURNAL ARTICLE

Structure investigations of Tl(I)-arsenates(V): Tl₃(AsO₄), Tl₂Cu(I)(AsO₄) and TlCu(II)₂(AsO₄)(AsO₃OH)

Year: 1998 Journal: Zeitschrift für Kristallographie - Crystalline Materials Vol: 213 (1)Pages: 42-46 Publisher: De Gruyter

DOI: 10.1524/zkri.1998.213.1.42

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Abstract

Abstract The three Tl(I)-arsenates(V) Tl 3 AsO 4 ) [ a = 8.517(3) Å, c = 5.233(2) Å, space group P 6 3 , Z = 2], Tl 2 Cu(I)(AsO 4 ) [ a = 6.000(3) Å, = 5.343(2) Å, c = 8.616(3) Å, β = 98.05(3)°, space group P 2 1 , Z = 2], and TlCu(II) 2 (AsO 4 )(AsO 3 OH) [ a = 6.407(2) Å, b = 11.245(4) Å, c = 10.173(3) Å, β = 98.64(2)°], space group P 2 1 / c , Z = 4] have been synthesized under hydrothermal conditions. Their structures were determined from single crystal X-ray diffraction data.

Keywords:

Crystallography Chemistry Group (periodic table) Crystal structure X-ray crystallography Hydrothermal circulation Nuclear chemistry Diffraction Physics Geology

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Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

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Structure investigations of Tl(I)-arsenates(V): Tl₃(AsO₄), Tl₂Cu(I)(AsO₄) and TlCu(II)₂(AsO₄)(AsO₃OH)

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