JOURNAL ARTICLE

[CuCl(C12H9N2O5)(C12H10N2O5)(H2O)]

M.J. RuizR. OrtizL. PerellóA. Castiñeiras

Year: 1999 Journal:   Acta Crystallographica Section C Crystal Structure Communications Vol: 55 (6)Pages: 878-880   Publisher: Wiley

Abstract

In the title compound, aquachloro(1-ethyl-1,4-dihydro-4-oxo-1,3-dioxolo[4,5-g]cinnoline-3-carboxylato-O 3 ,O 4 )-(1-ethyl-1,4-dihydro-4-oxo-1,3-dioxolo[4,5-g]cinnoline-3-carboxylic acid-O 3 ,O 4 )copper(II) the Cu II ion adopts a tetragonally distorted octahedral geometry. In the equatorial plane, the Cu II ion is coordinated to two O atoms (O keto and O carboxylate ) of one cinoxacinate ligand, and to two O atoms (O keto and O carboxylic ) of one cinoxacin molecule. The apical positions are occupied by one O atom from the water molecule and one Cl - ion, resulting in a CuClO 5 chromophore.

Keywords:
Materials science Analytical Chemistry (journal) Chemistry

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Topics

Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology
Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Synthesis and Characterization of Heterocyclic Compounds
Physical Sciences →  Chemistry →  Organic Chemistry

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