Synthesis and reactions of η<sup>3</sup>-5-oxocyclohexenyl(dicarbonyl)(η<sup>5</sup>-cyclopentadienyl)molybdenum

Anthony J. Pearson; Matthew W. D. Perry

doi:10.1039/c39890000389

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Synthesis and reactions of η³-5-oxocyclohexenyl(dicarbonyl)(η⁵-cyclopentadienyl)molybdenum

Anthony J. Pearson Matthew W. D. Perry

Year: 1989 Journal: Journal of the Chemical Society Chemical Communications Pages: 389-391 Publisher: Royal Society of Chemistry

DOI: 10.1039/c39890000389

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Abstract

Deprotonation of cyclohexadiene(dicarbonyl)(η5-cyclopentadienyl)molybdenum hexafluorophosphate (1) gives the η3-cyclohexadienyl complex (2) which is converted to the 5-oxocyclohexenyl complex (4) by hydroboration followed by Swern oxidation; generation of the enolate of (4) and its reactions with electrophiles are reported.

Keywords:

Cyclopentadienyl complex Molybdenum Hexafluorophosphate Hydroboration Chemistry Electrophile Swern oxidation Deprotonation Medicinal chemistry Organic chemistry Catalysis Ion

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Synthetic Organic Chemistry Methods

Physical Sciences → Chemistry → Organic Chemistry

Organometallic Complex Synthesis and Catalysis

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Synthesis and reactions of η³-5-oxocyclohexenyl(dicarbonyl)(η⁵-cyclopentadienyl)molybdenum

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Synthesis and reactions of η3-5-oxocyclohexenyl(dicarbonyl)(η5-cyclopentadienyl)molybdenum

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