JOURNAL ARTICLE

Preparation and Photocatalytic Activity of TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3 </sub>Nanocomposite

Su HuXuan Hui ZhangYing HeXian Chao HuLei ChengGuo Hua Li

Year: 2011 Journal:   Applied Mechanics and Materials Vol: 130-134 Pages: 2396-2399   Publisher: Trans Tech Publications

Abstract

TiO 2 /Fe 2 O 3 nanocomposite was fabricated by a hydrolysis-precipitation approach, with TiCl 4 as precursor and Fe 2 O 3 as support. The crystal phase, diameter and morphology of the sample particle were characterized by X-ray diffraction, transmission electron microscope. The results show that the samples are composed of haematite and rutile. The morphology and diameter of rutile particle, coating effect and weight percentages of haematite and rutile are related to the preparing temperature and molar ratio of Fe/Ti. The photocatalytic activity of the prepared photocatalyst was estimated in an aqueous solution at ambient temperature of 303K. The results imply that the photocatalytic activity of the sample is higher than that of phase pure rutile, related to Fe/Ti molar ratio and its preparing temperature. These results can be attribute to the microsturcture of the sample. A synergistic effect exists between titania and haematite in the nanocomposite.

Keywords:
Rutile Photocatalysis Materials science Nanocomposite Aqueous solution Precipitation Transmission electron microscopy Phase (matter) Chemical engineering Nuclear chemistry Molar ratio Hydrolysis Particle size Crystal (programming language) Mineralogy Nanotechnology Chemistry Catalysis Physical chemistry Organic chemistry

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Topics

TiO2 Photocatalysis and Solar Cells
Physical Sciences →  Energy →  Renewable Energy, Sustainability and the Environment
Advanced Photocatalysis Techniques
Physical Sciences →  Energy →  Renewable Energy, Sustainability and the Environment
Pigment Synthesis and Properties
Physical Sciences →  Chemistry →  Inorganic Chemistry

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