JOURNAL ARTICLE
Electrical conductivity in two mixed-valence liquids
Wenzhi YaoSteven P. KelleyRobin D. RogersThomas P. Vaid
Year: 2015 Journal: Physical Chemistry Chemical Physics Vol: 17 (21)Pages: 14107-14114 Publisher: Royal Society of Chemistry
Abstract
Two mixed-valence room-temperature liquids are reported: BuFc–[BuFc+][NTf2−] (BuFc =n-butylferrocene) and TEMPO–[TEMPO+][NTf2−]. Both are conductors of DC electrical current, and their conductivity is modeled based on the electron-transfer self-exchange rate constants of their constituent redox-active species.
Keywords:
Chemistry Electrical resistivity and conductivity Valence (chemistry) Conductivity Molar conductivity Reaction rate constant Molar concentration Analytical Chemistry (journal) Redox Ion Physical chemistry Crystallography Inorganic chemistry Kinetics Organic chemistry
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7
Cited By
0.36
FWCI (Field Weighted Citation Impact)
40
Refs
0.51
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Citation History
Topics
Ionic liquids properties and applications
Physical Sciences → Chemical Engineering → Catalysis
Electrochemical Analysis and Applications
Physical Sciences → Chemistry → Electrochemistry
Organic and Molecular Conductors Research
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
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