The binuclear μ-phenylvinylidene complex (η5-C5H5)(CO)(μ-CO)MnPt(μ-C=CHPh)(η2-Ph2PCH2PPh2)·Et2O

F.M. Dolgushin; Nina A. Deykhina; D. A. Pogrebnyakov; А.Б. Антонова

doi:10.1107/s1600536801017500

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The binuclear μ-phenylvinylidene complex (η⁵-C₅H₅)(CO)(μ-CO)MnPt(μ-C=CHPh)(η²-Ph₂PCH₂PPh₂)·Et₂O

F.M. Dolgushin Nina A. Deykhina D. A. Pogrebnyakov А.Б. Антонова

Year: 2001 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 57 (11)Pages: m541-m542 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536801017500

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Abstract

The title compound, [bis(diphenylphosphino)methane-2κ2P,P′]-μ-carbonyl-1:2κC-carbonyl-1κC-[1(η5)-cyclopentadienyl](μ-phenylvinylidene-1:2κ2C)manganeseplatinum(Mn—Pt) diethyl ether solvate, (η5-C5H5)(CO)(μ-CO)MnPt(μ-C=CHPh)(η2-Ph2PCH2PPh2)·Et2O or [MnPt(C5H5)(C8H6)(C25H22P2)(CO)2]·C4H10O, represents the first example of a structurally characterized μ-vinylidene Mn—Pt complex [Mn—Pt 2.6068 (10) Å]. Two metal atoms are bridged by a μ-phenylvinylidene ligand [Mn—C 1.924 (7), Pt—C 1.991 (6) and C=C 1.363 (9) Å] and an asymmetrical μ-carbonyl ligand [Mn—C 1.826 (7), Pt—C 2.212 (7), C—O 1.189 (8) Å, Mn—C—O 153.4 (6) and Pt—C—O 126.7 (5)°].

Keywords:

Chemistry Ligand (biochemistry) Medicinal chemistry Metal carbonyl Metal Diethyl ether Ether Vinyl ether Platinum Stereochemistry Crystallography Catalysis Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Hydrogenation and Catalysis

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The binuclear μ-phenylvinylidene complex (η⁵-C₅H₅)(CO)(μ-CO)MnPt(μ-C=CHPh)(η²-Ph₂PCH₂PPh₂)·Et₂O

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