Li<sub>2</sub>Sn(OH)<sub>6</sub>

Shoufeng Yang; Peter Y. Zavalij; M. Stanley Whittingham

doi:10.1107/s0108270100018710

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Li₂Sn(OH)₆

Shoufeng Yang Peter Y. Zavalij M. Stanley Whittingham

Year: 2001 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 57 (3)Pages: 228-229 Publisher: Wiley

DOI: 10.1107/s0108270100018710

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Abstract

Hydrothermally prepared dilithium tin hexahydroxide crystallizes in the monoclinic system (space group P2(1)/n), with the Sn atom at a site with -1 symmetry and all other atoms in general positions. The Sn coordination polyhedron is made up of six hydroxide groups. The Li atom is tetrahedrally coordinated by oxygen, with the tetrahedra sharing two corners and one edge with the adjacent Sn octahedra. Hydrogen bonds between the OH groups provide additional bonds in the framework.

Keywords:

Octahedron Crystallography Dilithium Monoclinic crystal system Group (periodic table) Tetrahedron Tin Atom (system on chip) Hydrogen bond Materials science Polyhedron Chemistry Crystal structure Molecule Ion Metallurgy Geometry Mathematics Computer science

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Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Chemical Synthesis and Characterization

Physical Sciences → Environmental Science → Industrial and Manufacturing Engineering

Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

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