Determination of Trace Amounts of Zinc by Flame Atomic Absorption Spectrometry After Preconcentration with Modified Clinoptilolite Zeolite

Abstract

Abstract Natural clinoptilolite was used as a sorbent material for solid-phase extraction and preconcentration of zinc. Clinoptilolite was first saturated with cadmium (II) and then modified with benzyldimethyltetradecylammonium chloride for increasing adsorption of 3-(2-arsenophenylazo)-4,5-dihydroxy-2,7-naphthalene disulfonic acid (neothorin). Zinc was quantitatively retained on the adsorbent by the column method in the pH range of 3.84.2 at a flow rate of 1 mL/min. It was eluted from the column with 5.0 mL 2 M nitric acid solution at a flow rate of 1 mL/min and determined by flame atomic absorption spectrometry at 213.9 nm. Zinc could be concentrated from a 0.03 g/L solution with a preconcentration factor of 170. Relative standard deviation for 8 replicate determinations of 2.5 g zinc in the final solution was 0.92. The interference of a large number of anions and cations was studied in detail to optimize the conditions, and the method was successfully applied for determination of zinc in standard and real water samples.