K3Ga2(PO4)3and Na3Ga(PO4)2

M. Beaurain; R. Astier; A. van der Lee; P. Armand

doi:10.1107/s0108270107061963

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K₃Ga₂(PO₄)₃and Na₃Ga(PO₄)₂

M. Beaurain R. Astier A. van der Lee P. Armand

Year: 2007 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 64 (1)Pages: i5-i8 Publisher: Wiley

DOI: 10.1107/s0108270107061963

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Abstract

The structures of tripotassium digallium tris(phosphate), K3Ga2(PO4)3, and trisodium gallium bis(phosphate), Na3Ga(PO4)2, have different irregular one-dimensional alkali ion-containing channels along the a axis of the orthorhombic and triclinic unit cells, respectively. The anionic subsystems consist of vortex-linked PO4 tetrahedra and GaO4 tetrahedra or GaO5 trigonal bipyramids in the first and second structure, respectively.

Keywords:

Orthorhombic crystal system Crystallography Tetrahedron Alkali metal Gallium Triclinic crystal system Hexagonal crystal system Trigonal crystal system Ion Chemistry Crystal structure Materials science

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Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Solid-state spectroscopy and crystallography

Physical Sciences → Materials Science → Materials Chemistry

Zeolite Catalysis and Synthesis

Physical Sciences → Chemistry → Inorganic Chemistry

K₃Ga₂(PO₄)₃and Na₃Ga(PO₄)₂

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