JOURNAL ARTICLE
ChemInform Abstract: New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8 (HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O.
Year: 2013 Journal: ChemInform Vol: 44 (45) Publisher: Wiley
Abstract
Abstract Rb 3 HGa 2 (OH) 2 (SeO 3 ) 4 (I), Rb 3 Ga 5 (SeO 3 ) 8 (HSeO 3 ) 2 ·0.5H 2 O (II), and RbGa(SeO 3 ) 2 ·H 2 O (III) are synthesized by hydrothermal reactions of appropriate amounts of Rb 2 CO 3 , Ga(NO 3 ) 3 , and SeO 2 (autoclave, 230 °C, 4 d, yields of 33%, 38%, and 40%, resp.).
Keywords:
Chemistry Hydrothermal circulation Autoclave Hydrothermal synthesis Characterization (materials science) Crystal structure Hydrothermal reaction Crystallography Alkali metal Octahedron Inorganic chemistry Nanotechnology Organic chemistry Chemical engineering
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Topics
Crystal Structures and Properties
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
Solid-state spectroscopy and crystallography
Physical Sciences → Materials Science → Materials Chemistry
Glass properties and applications
Physical Sciences → Materials Science → Ceramics and Composites
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