THERMAL DEHYDRATION OF BARIUM AND CALCIUM TRIMETAPHOSPHATE HEXAHYDRATES: Ba3(P3O9)26H2O AND Ca3(P3O9)26H2O

A. Thrierr-sorel; D. Tacquenet; Marie-Hélène Simonot-Grange

doi:10.1080/03086648008078164

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THERMAL DEHYDRATION OF BARIUM AND CALCIUM TRIMETAPHOSPHATE HEXAHYDRATES: Ba₃(P₃O₉)₂6H₂O AND Ca₃(P₃O₉)₂6H₂O

A. Thrierr-sorel D. Tacquenet Marie-Hélène Simonot-Grange

Year: 1980 Journal: Phosphorous and Sulfur and the Related Elements Vol: 8 (1)Pages: 73-78 Publisher: Taylor & Francis

DOI: 10.1080/03086648008078164

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Abstract

Abstract Ba3(P3O9)26H2O and Ca3(P3O9)26H2O have mobile H2O's which, under a dynamic vacuum of about 0.133 Pa, leave the lattice without disrupting it. Under water-vapor pressure, dehydration is accompanied by hydrolysis of P3O9 3- rings. The final product of dehydration is the β polyphosphate.

Keywords:

Dehydration Barium Polyphosphate Calcium Hydrolysis Chemistry Materials science Analytical Chemistry (journal) Inorganic chemistry Phosphate Nuclear chemistry Chromatography Organic chemistry Biochemistry

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THERMAL DEHYDRATION OF BARIUM AND CALCIUM TRIMETAPHOSPHATE HEXAHYDRATES: Ba₃(P₃O₉)₂6H₂O AND Ca₃(P₃O₉)₂6H₂O

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